WebDec 3, 2013 · An unusual 4e – oxidation of Cl – into ClO 2 – occurred during the reaction between CuCl and phenanthroline (phen) in air to form a [Cu(phen) 2]ClO 2 complex, … WebDec 22, 2024 · The chiral Cu(II) complexes [Cu(phen)(L-Val)(OH 2)](NO 3)∙2H 2 O (Figure 19a) and [Cu(phen)(D-Val)(ONO 2)]∙3H 2 O (Figure 19b) of Arjmand et al. shows anticancer potency in the micromolar order on breast (MCF-7), pancreatic (BxPC3, AsPC1) and liver (Huh7) cancer cells. Notably, these compounds are able to target G-quadruplex DNA …
Crystal structures, electronic properties and structural …
WebSep 1, 2012 · Cu(II) complexes with 1,10-orthophenanthroline (phen) show cytotoxic and antitumoral effects. To enhance and exploit these features, we studied complexes containing one or two phen units together with N,N′-substituted-imidazolidine-2-thione (L).We synthesized and structurally characterized the precursor molecule Cu(phen)(OH 2) 2 … WebMar 1, 2000 · After 2 weeks, blue prismatic single crystals were obtained. An X-ray diffraction analysis revealed that the compound consists of one discrete [Cu(phen) 2 Cl] cation, one free OH − anion and six solvent water molecules. The Cu(II) is five coordinated by two chelated phen rings intersecting at 51.50(0.08)° and one chloro atom. phil\u0027s moss landing ca
Cu-TMEDA catalyst 30698-64-7 - Sigma-Aldrich
WebMar 15, 2024 · ABSTRACT The formation of the binary Cu(II)-1,10ʹ-Phenanthroline (Phen, L) in aqueous solution was studied by means of electromotive force measurements (EMF). In addition, the Cu(II)-2,2ʹ-Bipyridine (Bipy, L) and Cu(II)-1,10ʹ-Phenanthroline ternary complexes were studied using the low molecular weight blood serum ligands: lactate … WebJan 25, 2024 · At pH 6.5, speciation indicates that the major species with a 1:2 Cu:Phen molar ratio would be Cu(Phen) 2 2+, as compared to Cu(Phen)(OH) 2 at pH 12.3. … WebDec 5, 2015 · Reaction of yellow elemental sulfur (S 8) with green [Cu(phen) 2 OH 2](ClO 4) 2 (1) in methanol at room temperature in equimolar proportion yields a turquoise blue … phil\u0027s moss landing closing down